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Heavy rain in Valencia flooded the tunnel and forced the La Liga game off minutes before kick-off.
Julian Alvarez returned from the bench but Atletico Madrid slumped to a shock 3-0 loss at Athletic Club.
Barcelona's first home LaLiga match ends in a 2-0 win, with Champions League opponents also confirmed.
Barcelona and Real Madrid face difficult home games against Athletic Club and Real Sociedad to kick off the 2026-27 LaLiga season.
Wales' 'greatest captain' is back — this time in the dugout, not the defence.